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New metal-organic frameworks for molecular hydrogen storage

New metal-organic frameworks for molecular hydrogen storage

Goals

Create new, affordable and environmentally-friendly MOFs for better H2 absorption through functionalization, also targeting pore opening to improve properties.

Innovations

Common and readily available MOFs will be modified on the metal sites and on the ligands, to create new materials with improved H2 storage properties. New building blocks, namely hydride-based ligands, will be used to significantly improve the storage of hydrogen molecules in pores. The other approach enabling decisive improvements is the design of a MOF whose pore opening is induced by hydrogen adsorption.

PhD student: Loïc Rochez Ladeuze

Promoter

Prof. Yaroslav Filinchuk
Université Catholique de Louvain

Co-promoter

Dr. Timothy Steenhaut
Université Catholique de Louvain
Prof. Johan Wouter
University of Namur

Research Center

Tasks

T08-1
Synthesis of MOFs, their modification on metal sites and ligands; study of hydrogen adsorption
T08-2
Use of hydride ligands to design high-density porous materials Use of hydride ligands to design high-density porous materials of H2
T08-3
MOF design with hydrogen adsorption-induced pore opening

Loïc Rochez Ladeuze conducts his research in the laboratory.

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